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With the fourth season of Gossip Girl set to kickoff on the CW, Sep. 13, it looks as though Blake Lively is starting things off scandalous as always. She was seen on Tuesday afternoon (Aug. 31) with new Gossip Girl star, Sam Page, shooting a scene in New York City. Wearing a sexy black top with the chest area slightly exposed, Blake plays the newest love interest of Sam.

We’ll have to wait and see just how long Sam can entertain Serena before she finds herself a new flavor of the week. Tune into CW on Sep. 13th at 9PM for the start of the new season.

MORE PHOTOS OF BLAKE LIVELY ON THE SET OF GOSSIP GIRL AHEAD!

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<img src='http://sphotos.ak.fbcdn.net/hphotos-ak-ash2/hs184.ash2/44675_1

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